When two metal centres are needed instead of one: exclusive induction of Z-DNA by dinuclear metal complexes.
نویسندگان
چکیده
The B- to Z-DNA transition was very efficiently induced by dinuclear nickel and copper complexes based on the 1,3-bis(1,5,9-triazacyclododecyl) propane ligand but not by the corresponding mononuclear complexes. This dramatically different behaviour is explained by the formation of a macrochelate of the dinuclear complexes to the DNA.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 14 شماره
صفحات -
تاریخ انتشار 2012